Product ID:266 CITROL
MSDS Date:02/16/1996
FSC:7930
NIIN:00N089538
Status Code:A
MSDS Number: CHWFY

SCHAEFFER MFG CO

102 BARTON ST
ST LOUIS, MO 83104
US

Emergency Phone: 800-325-9962

Info Phone: 314-966-5681

Cage: 0DUG2

SCHAEFFER MFG CO

ST LOUIS, MO 63104 US

Telephone: 314-966-5681

Cage: 0DUG2

D-LIMONENE (MFR CAS # 15989-27-5)

CAS: 5989-27-5

RTECS: GW6360000

Fraction By Weight: 35-45%

OSHA PEL N/K

ACGIH TLV: N/K

DIETHANOLAMINE (SARA 313) (CERCLA)

CAS: 111-42-2

RTECS: KL2975000

Fraction By Weight: 1-3%

OSHA PEL 3 PPM

ACGIH TLV: 0.46 PPM; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

GLYCOLS, POLYETHYLENE, MONO (NONYLPENYL) ETHER;

CAS: 9018-45-9

RTECS: MD0900000

Fraction By Weight: 3-5%

OSHA PEL N/K

ACGIH TLV: N/K

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 10-15%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9495

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUES, BLOOD,
KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER
ACETATE (EGBEA). (EXTRACTED FROM D HHS (NIOSH) PUB NO 90-118) .
ACUTE: INGEST: HARMFUL IF INGESTED. THIS PROD IS CORR TO MOUTH &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: ESOPHAGUS IF SWALLOWED. EYE: AT HIGH
CONC WHEN HEATED VAPS ARE IRRIT TO EYES, LIQ CNTCT PRODUCES SEV
IRRIT & POSS EYE BURNS. SKIN: SLIGHTLY IRRIT W/POSS REDNESS,
EDEMA/DRYNESS TO SKIN. INHAL : INHAL OF VAPS OF MIST MAY CAUSE
DIZZ,DORW & IRRIT TO THE MUCS MEMBS. CHRONIC: DIETHANOLAMINE HAS
BEEN (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGESTION: DO NOT INDUCE VOMITING. DRINK MILK OR WATER TO
DILUTE. SEEK MEDICAL ATTENTION IMMEDIATELY. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH SKIN WITH COPIOUS AMOUNTS OF SOAP AND
WATER. LAUNDER CONT AMINATED CLOTHING. INHALATION: REMOVE VICTIM TO
FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. EYES:
IMMEDIATELY FLUSH WITH CLEAR, COOL, CLEAN WATER FOR 30 MINUTES.
SEEK MEDICAL ATTN IMMED.

Flash Point Method:COC
Flash Point:145F,63C
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL FOAM, SAND, EARTH
WATERFOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . TREAT AS A CLASS B FIRE. AVOID BREATHING FUMES.
Unusual Fire/Explosion Hazard:VAPORS CAN BE DENSER THAN AIR AND TRAVEL
BACK TO IGNITION SOURCE CAUSING FLASHBACK TO OCCUR.

Spill Release Procedures:ABSORB SPILLS WITH ABSORBENT MATERIAL.
VENTILATE CONFINED SPACES. LARGE SPILLS SHOULD BE DIKE THEN PUMPED
INTO A TANK TRUCK OR DRUMS FOR DISPOSAL. AFTER MATERIAL HAS BEEN
REMOVED, FLUSH CONTAMINATED A REA WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE NEAR HEAT, SPARKS OR OPEN
FLAMES. KEEP CONTAINER CLOSED WHEN PRODUCT IS NOT IN USE. FLAMMABLE
ACCORDING TO CURRENT DOT REGULATIONS.
Other Precautions:SPECIAL COMMENTS: THIS PRODUCT IS A COMBUSTIBLE
LIQUID. DO NOT REUSE CONTAINER. DISPOSE OF THE CONTAINER IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL EPA REGULATIONS. DO NOT
STORE NEAR FOOD PRODUCTS.

Respiratory Protection:NONE REQUIRED UNDER ORDINARY CONDITIONS OF USE.
NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NO SPECIAL REQUIREMENT UNDER ORDINARY CONDITIONS OF USE AND
WITH ADEQUATE VENTILATION.
Protective Gloves:SOLVENT RESISTENT NEORPENE/RUB GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USE APRON & BOOTS AS REQUIRED.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY WITH SOAP AND WATER AFTER USE.
Supplemental Safety and Health
EFTS OF OVEREXP: LINKED TO LIVER AND KIDNEY DAMAGE IN ANIMAL STUDIES.

Boiling Pt:B.P. Text:>212F,>100C
Spec Gravity:0.9313
pH:9
Solubility in Water:SOLUBLE
Appearance and Odor:THIS PRODUCT IS AVAILABLE IN SPRAY CANS.
Percent Volatiles by Volume:70

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH HEAT, SPARKS & OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES AND
KETONES.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL LAWS & REGULATIONS. FOR SPENT PRODUCT,
ALLOW OILS AND OILY WASTES TO SPARATE, SKIM OFF TOP OIL LAYER AND
DISCHARGE BOTTOM LAYER IN ACCORDANCE WITH EPA, FEDERAL, STATE &
LOCAL REGS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.